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Abstract Black carbon (BC) from fossil fuel and biomass combustion darkens the snow and makes it melt sooner. The BC footprint of research activities and tourism in Antarctica has likely increased as human presence in the continent has surged in recent decades. Here, we report on measurements of the BC concentration in snow samples from 28 sites across a transect of about 2,000 km from the northern tip of Antarctica (62°S) to the southern Ellsworth Mountains (79°S). Our surveys show that BC content in snow surrounding research facilities and popular shore tourist-landing sites is considerably above background levels measured elsewhere in the continent. The resulting radiative forcing is accelerating snow melting and shrinking the snowpack on BC-impacted areas on the Antarctic Peninsula and associated archipelagos by up to 23 mm water equivalent (w.e.) every summer. 

Outstanding questions about the RNA world hypothesis for the emergence of life on Earth concern the stability and self-replication of prebiotic aqueous RNA. Recent experimental work has suggested that solid substrates and low temperatures could help resolve these issues. Herein, we use classical molecular dynamics simulations to explore the possibility that the substrate is ice itself. Simulations at −20 °C show that an eight-nucleotide single strand of RNA, initially situated in the quasiliquid layer at the air/ice interface, exhibits a robust propensity to reorient itself -- its bases turn toward the (hydrophobic) air/ice interface, while its anionic phosphodiester oxygens align with the underlying ice lattice. Kinetic analysis of hydrogen bonding indicates resistance to hydrolysis that is greater than that of an aqueous single-strand RNA at the same temperature. This enhanced resistance, in turn, could increase the opportunities for polymerization and self-copying. These findings thus offer the possibility of a role for an ancient RNA world on ice distinct from that considered in extant elaborations of the RNA world hypothesis. This work is, to the best of our knowledge, the first molecular dynamics study of RNA on ice. 

Clouds have a large effect on the radiation budget and represent a major source of uncertainty in climate models. Supercooled liquid clouds can exist at temperatures as low as 235 K, and the radiative effect of these clouds depends on the complex refractive index (CRI) of liquid water. Laboratory measurements have demonstrated that the liquid‐water CRI is temperature‐dependent, but corroboration with field measurements is difficult. Here we present measurements of the downwelling infrared radiance and in‐situ measurements of supercooled liquid water in a cloud at temperatures as low as 240 K, made at South Pole Station in 2001. These results demonstrate that including the temperature dependence of the liquid‐water CRI is essential for accurate calculations of radiative transfer through supercooled liquid clouds. Furthermore, we show that when cloud properties are retrieved from infrared radiances (using the spectral range 500–1,200 cm⁻¹) spurious ice may be retrieved if the 300 K CRI is used for cold liquid clouds (∼240 K). These results have implications for radiative transfer in climate models as well as for retrievals of cloud properties from infrared radiance spectra.

 

Abstract. Improvements to climate model results in polar regions require improvedknowledge of cloud properties. Surface-based infrared (IR) radiancespectrometers have been used to retrieve cloud properties in polar regions,but measurements are sparse. Reductions in cost and power requirements toallow more widespread measurements could be aided by reducing instrumentresolution. Here we explore the effects of errors and instrument resolutionon cloud property retrievals from downwelling IR radiances for resolutionsof 0.1 to 20 cm−1. Retrievals are tested on 336 radiance simulationscharacteristic of the Arctic, including mixed-phase, verticallyinhomogeneous, and liquid-topped clouds and a variety of ice habits.Retrieval accuracy is found to be unaffected by resolution from 0.1 to 4 cm−1, after which it decreases slightly. When cloud heights areretrieved, errors in retrieved cloud optical depth (COD) and ice fractionare considerably smaller for clouds with bases below 2 km than for higherclouds. For example, at a resolution of 4 cm−1, with errors imposed(noise and radiation bias of 0.2 mW/(m2 sr cm−1) and biases intemperature of 0.2 K and in water vapor of −3 %), using retrieved cloudheights, root-mean-square errors decrease from 1.1 to 0.15 for COD, 0.3 to0.18 for ice fraction (fice), and 10 to 7 µm for iceeffective radius (errors remain at 2 µm for liquid effective radius).These results indicate that a moderately low-resolution, surface-based IRspectrometer could provide cloud property retrievals with accuracycomparable to existing higher-resolution instruments and that such aninstrument would be particularly useful for low-level clouds.